Caracterización de pigmentos extraídos de algas rojas de la Antártida para su posible uso en celdas solares del tipo DSSC

Autores

  • Micaela De Bon 1Laboratorio de Biomateriales, Facultad de Ciencias, Universidad de la República, UdelaR, Montevideo, Uruguay
  • Joaquín Hurtado Laboratorio de Biomateriales, Facultad de Ciencias, Universidad de la República, UdelaR, Montevideo, Uruguay
  • Paula Enciso Laboratorio de Biomateriales, Facultad de Ciencias, Universidad de la República, UdelaR, Montevideo, Uruguay.
  • Simona Armeli Minicante Istituto di Scienze Marine (ISMAR-CNR), Consiglio Nazionale delle Ricerche, Venezia, Italia
  • María Fernanda Cerdá Bresciano Laboratorio de Biomateriales, Facultad de Ciencias, UdelaR, Uruguay

DOI:

https://doi.org/10.26461/14.02

Palavras-chave:

ficoeritrina, algas rojas, DSSC

Resumo

En este trabajo se realizó la extracción en medio acuoso de ficoeritrina proveniente de algas rojas de la Isla Rey Jorge. Las especies que mostraron mejores rendimientos de extracción fueron Palmaria decipiens y Delesseria lancifolia. Esta ficoeritrina mostró un comportamiento adecuado para su uso como sensibilizador en celdas de tipo DSSC (dye sensitized solar cells), con altos valores de absorbancia, buena estabilidad con la temperatura y adecuado potencial redox.

Downloads

Não há dados estatísticos.

Referências

Armeli Minicante, S., Ambrosi, E., Back, M., Barichello, J., Cattaruzza, E., Gonella, F., Scantamburlo, E. y Trave, E., 2016. Development of an eco-protocol for seaweed chlorophylls extraction and possible applications in dye sensitized solar cells. En: Journal of Physics D: Applied Physics, 49, pp.295601–295608.

Armeli Minicante, S., Citro, I., Morabito, M., Genovese, G. y Calogero, G., 2015. Algal pigments as dye sources in the solar photovoltaic technology. En: Journal of Biological Research, 88, pp.28.

Bisquert, J., Cahen, D., Hodes, G., Rühle, S. y Zaban, A., 2004. Physical chemical principles of photovoltaic conversion with nanoparticulate, mesoporous dye-sensitized solar cells. En: Journal of Physical Chemistri B, 108, pp.8106–8118.

Bhogaita, M., Shukla, A.D. y Nalini, R.P., 2016. Recent advances in hybrid solar cells based on natural dye extracts from Indian plant pigment as sensitizers. En: Solar Energy, 137, pp. 212–224.

Cerdá M.F. y Enciso P., 2014.Caracterización de las antocianinas de la flor de ceibo como sensibilizadores naturales para su uso en celdas fotovoltaicas. En: INNOTEC, 9, pp.91–96.

Cao, Y.M., Bai, Y., Yu, Q.J., Cheng, Y.M., Liu, S., Shi, D., Gao, F.F. y Wang, P., 2009. Dye-sensitized solar cells with a high absorptivity ruthenium sensitizer featuring a 2-(Hexylthio)thiophene conjugated bipyridine. En: Journal of Physical Chemistry C, 113, pp.6290–6297.

Chen, C.Y., Wang, M.K., Li, J.Y., Pootrakulchote, N., Alibabaei, L., Ngoc-le, C.H., Decoppet, J.D., Tsai, J.H., Grätzel, C., Wu, C.G., Zakeeruddin, S.M. y Grätzel M., 2009. Highly efficient light-harvesting ruthenium sensitizer for thin-film dye-sensitized solar cells. En: American Chemical Society, 3, pp.3103–3109.

D’Agnolo, E., Rizzo, R., Paoletti, S. y Murano E., 1994. R-phycoerythrin from the red alga Gracilaria Longa. En: Phytochemistry, 35, pp.693–696.

Enciso, P., Cabrerizo, F.M.,Gancheff, J., Denis, P. y Cerdá, M.F., 2013. Phycocyanin as potential natural dye for its use in photovoltaic cells. En: Journal of Applied Solution Chemistry and Modelling, 24, pp.25–233.

Enciso, P. y Cerdá, M.F., 2016. Solar cells based on the use of photosensitizers obtained from Antarctic red algae. En: Cold Regions Science Technology, 126, pp.51–54.

Enciso, P., Decoppet, J.D.,Grätzel, M., Wörner, M., Cabrerizo, F.M. y Cerdá, M.F., 2017. A cockspur for the DSS cells: Erythrinacrista-galli sensitizers. En: Spectrochimica Acta Part A: Molecular and Biomolecular Spectroscopy, 176, pp.91–98.

Enciso, P., Decoppet, J.D.,Moehl, T., Grätzel, M., Wörner, M. y Cerdá M.F., 2016. Influence of the adsorption of phycocyanin on the performance in DSS cells: and electrochemical and QCM evaluation. International. En: Journal of Electrochemistry. Science, 11, pp.3604–3614.

Enciso, P., Minini, L., Álvarez, B. y Cerdá, M.F., 2012. Ensamblado de ficocianina sobre TiO2 nanoestructurado para celdas fotovoltaicas. En: INNOTEC, 7, pp.69–74.

Ficner, R. y Huber, R., 1993. Refined crystal structure of phycoerythrin from Porphyridiumcruentum at 0.23-nm resolution and localization of the subunit. En: European Journal of Biochemistry, 218, pp.103-106.

Gao, F., Wang, Y., Shi, D., Zhang, J., Wang, M.K.,Jing, X.Y., Humphry-Baker, R., Wang, P., Zakeeruddin, S.M. y Grätzel, M., 2008. Enhance the optical absorptivity of nanocrystalline TiO2 film with high molar extinction coefficient ruthenium sensitizers for high performance dye-sensitized solar cells. En: Journal of American Chemical Society, 130, pp.10720–10728.

Glazer, A.N., West, J.A. y Chan, C., 1982. Phycoerythrins as chemotaxonomic markers in red algae: a survey. En: Biochemical Systematics and Ecology, 10, pp.333–215

Isailovic, D., Li, H.W. y Yeung, E.S., 2004. Isolation and characterization of R-phycoerythrin subunits and enzymatic digests. En: Journal of Chromatography A, 1051, pp.119–130.

Kakiage, K., Aoyama, Y., Yano, T., Oya, K., Fujisawa, J.-I. y Hanaya, M., 2015. Highly-efficient dye-sensitized solar cells with collaborative sensitization by silyl-anchor and carboxy-anchor dyes. En: Chemical Communications, 51, pp. 15894-15897.

Liu, L.N., Su, H.N., Yan, S.G., Shao, S.M., Xie, B.B., Chen, X.L., Zhang, X.Y., Zhou, B.C. y Zhang, Y.Z., 2009. Probing the pH sensitivity of R-phycoerythrin: Investigations of active conformational and functional variation. En: Biochimica et Biophysica Acta 1787, pp.939–946.

Munier, M., Jubeau, S., Wijaya, A., Morançais, M., Dumay, J., Marchal, L., Jaouen, P. y Fleurence, J., 2014. Physicochemical factors affecting the stability of two pigments: R-phycoerythrin of Grateloupia turuturu and B-phycoerythrin of Porphyridium cruentum, En: Food Chemistry, 150, pp. 400-407.

Prabavathy,N., Shalini, S., Balasundaraprabhu, R., Velauthapillai, D., Prasanna, S. y Muthukumarasamy, N., 2017. Enhancement in the photostability of natural dyes for dye-sensitized solar cell (DSSC) applications: a review. En: International Journal of Energy Research, 41(10), pp. 1372-1396. DOI: 10.1002/er.3703.

Arquivos adicionais

Publicado

2017-11-27

Como Citar

De Bon, M., Hurtado, J., Enciso, P., Armeli Minicante, S., & Cerdá Bresciano, M. F. (2017). Caracterización de pigmentos extraídos de algas rojas de la Antártida para su posible uso en celdas solares del tipo DSSC. INNOTEC, (14 jul-dic), 44–49. https://doi.org/10.26461/14.02

Edição

Seção

Artículos

Artigos mais lidos pelo mesmo(s) autor(es)